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During the present work, the passive film properties were obtained from a local anodic dissolution test. In addition, the compactness of the passive film was assessed by AFM. The assessment of the passive film compactness was performed on aluminum oxide (AlOx) coatings on the 17-4PH MSS after the EAC tests. The AlOx coating thickness had already been studied in detail by Thevenot et al. [36]; they found that the AlOx thickness was about 10 nm after 100 hours of exposure in a 0.05 M NaCl solution. In the present work, after the EAC tests, the AlOx coating thickness measured was about 15 nm. Therefore, the assessment of the passive film compactness was in accordance with that obtained by the previous authors. Furthermore, as the thickness of the passive film was much lower for the L-PBF MSS than for the conventional MSS, it seemed that the influence of the passive film properties was very clear. In that sense, L-PBF MSS was much more permeable to the corrosion products than the conventional MSS; thus, any active removal processes led to a significant decrease in the thickness of the passive film. Consequently, pits were formed more frequently, which accelerated the transformation of the passive film in an active layer that was more permeable to the corrosion products. Therefore, a self-sustaining process was established and the EAC susceptibility increased.
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